Download e-book for iPad: Biochemistry of the Elemental Halogens and Inorganic Halides by Kenneth L. Kirk

By Kenneth L. Kirk

ISBN-10: 1468458175

ISBN-13: 9781468458176

ISBN-10: 1468458191

ISBN-13: 9781468458190

The components in team 17 (VIlA) of the periodic desk of elements-fluorine (F), chlorine (CI), bromine (Br), and iodine (I)-were targeted by means of Berzelius as "halogens" (Greek hals, sea salt; gennao, I beget) as a result of their propensity to shape salts. during this first of the 2 volumes of Bio­ chemistry of the Halogens, the biochemistry of the basic halogens and inorganic halides is reviewed. Discovery, homes, and biochemistry of the basic halogens are reviewed first (Chapter 1). this is often through a evaluation of the advancements within the quite a few components of inorganic halide biochemistry (Chapters 2 via 5). The biochemistry of thyroid hor­ mones is taken into account in bankruptcy 6, whereas biohalogenation, a huge hyperlink among inorganic and natural halogen biochemistry, is reviewed in bankruptcy 7. bankruptcy eight covers the biochemistry of goods produced through human-inspired halogenation, specifically, poly halogenated compounds that current environmental difficulties. In bankruptcy nine, the method is reversed and biodehalogenation is reviewed. In every one topic, the try out has been made to discover a suitable stability among intensity and breadth of remedy, because a radical, in­ intensity overview of this box wouldn't be attainable in one quantity. to supply readers now not acquainted with topics with the mandatory historical past to put next discussions in standpoint, short ancient advance­ ments of some of the subject matters are given.

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Extra resources for Biochemistry of the Elemental Halogens and Inorganic Halides

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Thus, the requirement for Pi again required an explanation. The first detailed kinetic study was carried out by Cimasoni (1972), a study that confirmed that F - alone exhibited very weak (uncompetitive) inhibition. However, inhibition was strong and competitive in the presence of Pi. Cimasoni suggested that, in the absence of Pi' F- binds to the substrate-enzyme complex but, in the presence of Pi' F- binds directly to the enzyme and thus displays competitive inhibition. In another kinetic study, Wang and Himoe (1973) examined the effects of varying concentrations of Mg2+, Mn2+, F-, and Pi on the rate of enolase··catalyzed dehydration.

1985. Formation of aryl-chlorinated aromatic acids and precursors for chloroform in chlorination of humic acid, in Water Chlorination. Chemistry, Environmental Impact and Health Effects, Vol. 5 (R. L. Jolley, R. J. Bull, W. P. Davis, S. Katz, M. H. , and V. A. ), Lewis Publishers, Chelsea, Michigan, pp. 843-857. Ellis, J. , and May, G. , 1986. Modern fluorine generation, J. Fluorine Chem. 33:133-146. , 1986. The life and scientific work of Henri Moissan, J. Fluorine Chem. 33:27-42. Fukayama, M.

Davis, W. , and Roberts, M. , 1985. Water chlorination: Crossroad of uncertainties and decisions, in Water Chlorination. Chemistry, Environmental Impact and Health Effects, Vol. 5 (R. L. Jolley, R. J. Bull, W. P. Davis, S. Katz, M. H. , and V. A. ), Lewis Publishers, Chelsea, Michigan, pp. 3-4. de Leer, E. W. , Damste, J. S. , 1985. Formation of aryl-chlorinated aromatic acids and precursors for chloroform in chlorination of humic acid, in Water Chlorination. Chemistry, Environmental Impact and Health Effects, Vol.

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Biochemistry of the Elemental Halogens and Inorganic Halides by Kenneth L. Kirk


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