Download e-book for iPad: Colloid Science: Principles, Methods and Applications by Terence Cosgrove

By Terence Cosgrove

ISBN-10: 1405126736

ISBN-13: 9781405126731

ISBN-10: 1405168382

ISBN-13: 9781405168380

Colloidal structures are vital throughout various industries, akin to the nutrition, pharmaceutical, agrochemical, cosmetics, polymer, paint and oil industries, and shape the foundation of a variety of items (eg cosmetics & toiletries, processed foodstuffs and photographic film). an in depth figuring out in their formation, keep an eye on and alertness is needed in these industries, but many new graduate or postgraduate chemists or chemical engineers have very little direct event of colloids.This publication relies on lectures given on the hugely profitable Bristol Colloid Centre Spring tuition, designed to supply a radical creation to colloid technology for commercial chemists, technologists and engineers. The direction has attracted a variety of industrialists from significant businesses with over a thousand delegates attending in all. This publication brings jointly the BCC Spring institution lectures and provides them in a coherent and logical textual content on functional colloid technological know-how. The authors are popular the world over of their respective fields and the publication may be uniquely focussed on delivering the reader with a close realizing of the sensible software of colloid technological know-how.

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Extra info for Colloid Science: Principles, Methods and Applications

Sample text

2 Interaction limited coagulation When there is an energy barrier to prevent the particles coming together the rate is slowed, as only a fraction of the particles collide with sufficient energy to exceed the height of the barrier and stick. This is known as reaction limited aggregation with a rate constant k R in contrast to the diffusion limited rate constant k D . 16) To a good approximation the reaction limited diffusion rate constant is proportional to the Boltzmann factor which gives the fraction of particles at any instant with energy in excess of the primary maximum.

6, 366–371. 2. O’M. N. (2000) Modern Electrochemistry, 2nd edition. Plenum, New York. 3. C. (1947) The electrical double layer and the theory of electrocapillarity. Chem. , 41, 441–501. 4. Delahay, P. (1965) Double Layer and Electrode Kinetics. Interscience, New York. 5. , Hendrikse, J. and van der Berg, A. (1999) Field-effect fluid control for microfabricated fluidic networks. Science, 286, 942–945. 6. E. (1981) Laser Doppler methods in electrophoresis. Prog. Surf. , 10, 53–164. 7. , Tscharnuter, W.

When two charged particles come together there are two extreme cases which we can envisage. If the ion adsorption equilibrium is maintained then either the surface charge remains constant and the surface potential compensates (constant charge) or the surface potential remains constant and the surface charge density changes to compensate (constant potential). Hogg et al. [2] derived expressions which enable us to calculate the interaction between non-identical spheres under both constant charge and constant potential conditions.

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Colloid Science: Principles, Methods and Applications by Terence Cosgrove


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